Modified Acrylic Resins, Formulated Performance to Meet Customer Needs.

Ashland has developed a series of unique thermoset polymers called MODAR Modified Acrylic Resins. These resins were initially developed for closed molding applications such as resin transfer molding and pultrusion. However, the end use properties of MODAR resins have encouraged their use also in other molding processes, such as hand layup, vacuum infusion (scrimp) and filament winding.

This unique chemistry offers a very diversified range of applications in many markets like automotive, mass transit, railways, building, rods for optical cable, structural parts and profiles, and optimal fire retardant / low smoke composite parts.

MODAR resins can be used in carbon fibers reinforced composites in place of epoxies. MODAR resins offer faster cure times and competitive physical properties. MODAR resins are based on methacrylate chemistry and they are processed like unsaturated polyester resins by free-radical cross-linking.

MODAR Resins Inherently Offer:


  • low viscosity
  • rapid cure
  • fast cycle times
  • superior physical properties
  • resistance to cracking
  • long shelf-life and stability (valuable for hot climate countries)
MODAR resin systems with low profile additive for class A surface (MODAR 824LTS) or with low shrink additive for pultrusion (MODAR 826HT) give high quality surface finish and good dimension stability.


MODAR resins with aluminium trihydrate are an outstanding solution for fire retardant applications (FR/LS).


These blends meet the most stringent fire requirements for fire retardancy, ignitability, rate of heat release, smoke generation, and toxicity (non-halogenated resins). This solution allows to produce FR/LS composite parts with a standard process and a good balance of properties like toughness, surface quality and high productivity.

    AROTRAN, World Leading Technology and Solutions for the Automotive Market.

    Ashland Composite Polymers is recognized as a leader in unsaturated polyester, vinyl ester, and low profile resins for the thermoset composites industry. Our resins are specified for all types of reinforced composite applications. Through our research and development efforts, various resins and components have been commercialized for the transportation market.

    AROTRAN® Resins provide a complete package of technologies and solutions to the automotive market. From Class A body panels, structural, underhood, and molded in color, black, UV stable SMC formula for truck box applications, Ashland has a technology for your needs.  Our “world class” technical service group provides custom formulating and process mold trouble shooting to insure a quality component that will meet or exceed OEM requirements.  Our “best-in-class” marketing group in Detroit will work with your advance sales and engineering workforce to insure the right material choice for ultimate properties at the lowest cost.

    The AROTRAN Resin Product Line Has These Technologies to Offer`:

    • Phase Epsilon™ 50411 Premium Class A body panel resin offers exceptional paint, bonding and physical property performance.
    • Phase Delta™ 50425 Class A body panel resin offers low moisture/e-coat capable, exceptional paint, bonding and physical properties.
    • HIPPI 50418 High Performance Resin for Inners is a versatile resin that can take high loading of filler and glass and is a low cost system with zero shrink capabilities.
    • Arotech™ 2000, 2002, 2005 high performance vinyl ester resins for structural and underhood applications offer consistent thickening.
    • Envirez™ 5000 corn and soybean grain derived organic resin composition comes from renewable sources and has excellent surface quality, exceptional paint, bonding and physical property performance.
    • Ekadure™ 2001 Structural, UV stable, black SMC resin which has molded in color that eliminates the need for paint in truck box applications, excellent weathering capability and mechanical properties. (Developed in technology partnership with Plasticolors Inc., Ashtabula, Ohio, USA)
    • Low Profile Additives, such as polyesters, hybrid urethane,  polyvinyl acetate, polymethyl methacrylate and polystyrene, offer a one stop shop for shrinkage control, fiber readthrough control and improved surface enhancements.

    Corrosion Resistant Epoxy Vinyl Ester Resins and Fire Retardant Resins

    Ashland is a leading supplier of corrosion resistant resins for reinforced plastics. We offer the most comprehensive line of corrosion resistant, heat resistant and fire retardant resins on the market today. Ashland’s experience spans five decades.

    No Single FRP Resin Can Handle Every Kind of Corrosion Problem


    That´s why Ashland has made a wide range of famous HETRON® corrosion resistant epoxy vinyl ester resins to fit all customers’ needs. HETRON epoxy vinyl ester resins differ from polyesters due to their enhanced mechanical properties. HETRON resins offer excellent physical strength and improved impact and thermal shock resistance compared to regular polyester resins. HETRON epoxy vinyl ester resins are also available as low styrene content (<35%) versions.

    Maximum Corrosion Resistance with HETRON Resins

    HETRON epoxy vinyl ester resins offer maximum corrosion and temperature resistance to acids, alkalis, hypochlorites and many solvents. HETRON corrosion resistant products have been formulated by using the F-Cat technology (see pages 16-17) for flexibility in production. The HETRON resin technical service group provides recommendations and specific services at hetron@ashland.com.

    HETRON Fire Retardant Resins


    Ashland´s range of HETRON fire retardant resins is the broadest in the industry. You can find HETRON resins with or without halogens incorporated into the polymer backbone. HETRON fire retardant resins can be based on epoxy vinyl ester or unsaturated polyester technology. Due to their excellent fire retardant properties, HETRON resins have been successfully used in building and construction (wall cladding, panels, roofing, shower cabins), in infrastructure (panels, electrical boxes, bus shelters, street lamps), in transport (interior and exterior parts in trains, buses, trams, subways) and in marine (rescue boats, patrol vessels, luxury cruiser interior parts). 

    The HETRON resin family includes products tested according to both national (NF, DIN, BS, UNE, etc.) and international (EU, UL, IMO, etc.) classification requirements.

    The Complete Technology Composite Polymers

    Composites and caste polymer products have one special feature; the material, a combination of matrix resin, reinforcements and fillers, is born at the same time as the final product is manufactured. This sets stringent requirements on all of us in the production chain, from petrochemicals to thermostat polymers and further to the final fiber reinforced or caste polymer product.

    A High-Performance Family of Products


    AROPOL™ is the family name for Ashland’s complete range of unsaturated polyester resins serving the composites industry. We believe that superior end products are created with successful cooperation between raw material suppliers and composites producers. Suppliers’ skills and service capabilities are essential to fully utilize the properties of composites and casted polymer products. That is why Ashland Composite Polymers has a skillful and extensive organization of professionals for every customer in every area we serve. Our network of plants, sales representatives, technical support and distributors work hard to ensure we deliver the performance our customers need.
     

    Better Working Environment and Savings in Raw Material Consumption


    We also work constantly on improving production methods at our plants, implementing quality systems, such as ISO 9001, ISO 14001, and the standard of Det Norske Veritas for Occupational Health and Safety Assessment System, and incorporating the Responsible Care guiding principles into every aspect of our plant operations.

    Many of the AROPOL products are also formulated to meet the toughest requirements set by international classification Societies like Lloyds’ Register, Det Norske Veritas, Afnor, Rina, British Standard Institute, Germanisher Lloyd and ANSI.

    Our salespeople and technical service team will guide you in finding the right AROPOL resin for your product and your application process.

    Products for Composites and Cast Polymers

    AOC is a leading global supplier of unsaturated polyesters, vinyl esters, gel coats, additives and dispersions for composites and cast polymers. AOC technologies encompass all open and closed mold manufacturing processes and serve all end-use market sectors.  AOC helps develop complete material systems that are backed by a technical support team who offers comprehensive, cost-saving solutions.  AOC technical expertise covers all areas, including low- styrene formulations that process and perform as well as or, in many cases, better than traditional resins and gel coats.  DOWNLOAD